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Name Minghuey Shieh
Lab TEL (02)77496187; (02)77496188
Office TEL (02)77496118
FAX No. (02)29309081
Address. (11677)No. 88, Sec. 4, Ting-Chow Rd, Taipei, Taiwan, 11677, R.O.C.
E-mail mshieh@ntnu.edu.tw
Lab. Website http://www.chem.ntnu.edu.tw/~MShieh/index.html
Classification Full-Time
Title Professor
Research Metal Cluster Chemistry, Organometallics, Material Chemistry, Computational Chemistry
Research Specialization Major goals of our research include synthetic, magnetic, electrochemical, and theoretical studies of heavier main group elements-containing transition metal carbonyl clusters.
Laboratory Metal Cluster Chemistry Lab /

Academic Researches

  1. Journal Articles
    1. M. Shieh,* C.-C. Yu, K.-J. Hsing and W.-J. Chang, “The Well-Defined Bismuth(III) in a Multiply Bonded Trigonal-Planar Complex with Prodigious Lewis Acidity,Chem.Eur. J., 2017, 23, 11677─11683.
    2. M. Shieh,* C.-C. Yu, C.-Y. Miu, C.-H. Kung, C.-Y. Huang, Y.-H. Liu, H.-L. Liu and C.-C. Shen, “Semiconducting Coordination Polymers Based on the Pre-Designed Ternary Te–Fe–Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers,Chem.Eur. J., 2017, 23, 11261─11271.
    3. M. Shieh,* C.-Y. Miu, Y.-H. Liu, Y.-Y. Chu, K.-J. Hsing, J.-I Chiu and C.-F. Lee, “Ternary Se─Ru─Cu Clusters: Facile Synthesis, Electrochemistry, and UV/Vis Absorption,” J. Organomet. Chem., 2016, 815816, 74─83.
    4. C.-N. Lin, C.-Y. Huang, C.-C. Yu, Y.-M. Chen, W.-M. Ke, G.-J. Wang, G.-A. Lee and M. Shieh,* “Iron Carbonyl Cluster-Incorporated Cu(I) NHC Complexes in Homocoupling of Arylboronic Acids: an Effective [TeFe3(CO)9]2− Ligand ,Dalton Trans., 2015, 44, 16675─16679.
    5. M. Shieh,* C.-Y. Miu, K.-J. Hsing, L.-F. Jang and C.-N. Lin, “Copper-Incorporated Mono- and Di-TeRu5 Metal Carbonyl Complexes: Syntheses, Structures, and an Unusual Skeletal Arrangement,Dalton Trans., 2015, 44, 6526─6536.
    6. M. Shieh,* Y.-Y. Chu, L.-F. Jang and C.-H. Ho, “CO and CO2 Fixation by SeRuCO Hydride Clusters,” Inorg. Chem., 2014, 53, 4284─4286.
    7. C.-N. Lin, W.-T. Jhu and M. Shieh,* “Vapochemically and Mechanochemically Reversible Polymerization/Depolymerization of SFeCu Carbonyl Clusters,“ Chem. Commun., 2014, 50, 1134-1136.
    8. M. Shieh,* C.-H. Yu, Y.-Y. Chu, Y.-W. Guo, C.-Y. Huang, K.-J. Hsing, P.-C. Chen and C.-F. Lee, “Trigonal Bipyramidal and Square Pyramidal ChromiumManganese Chalcogenide Clusters [E2CrMn2(CO)n]2 (E = S, Se, Te; n = 9, 10): Synthesis, Electrochemistry, UV/Vis Absorption, and Computational Studies,” Chem. Asian J., 2013, 8, 963-973.
    9. M. Shieh,* C.-Y. Huang, C.-J. Lee,K.-J. Hsing, Y.-W. Li, Y.-Y. Chu and W.-T. Jhu, “Controlled Synthesis of Copper Halide-IncorporatedTriiron Carbonyl Sulfide Clusters: Synthesis, Electrochemistry, and Computational Studies,” Polyhedron, 2013, 52, 879-889.
    10. M. Shieh,* C.-Y. Miu, Y.-Y. Chu and C.-N. Lin, “Recent Progress in the Chemistry of Anionic Groups 6─8 Carbonyl Chalcogenide Clusters,” Coord. Chem. Rev., 2012, 256, 637-694.
    11. M. Shieh,* C.-Y. Miu, K.-C. Huang, C.-F. Lee and B.-G. Chen, “Stepwise Construction of Manganese─Chromium Carbonyl Chalcogenide Complexes: Synthesis, Electrochemical Properties, and Computational Studies,” Inorg. Chem., 2011, 50, 7735-7748.
    12. M. Shieh,* Y.-Y. Chu, M.-H. Hsu, W.-M. Ke and C.-N. Lin, “Lead-Chromium Carbonyl Complexes Incorporated with Group 8 Metals: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem., 2011, 50, 565-575.
    13. C.-H. Ho, Y.-Y. Chu, C.-N. Lin, H.-W. Chen, C.-Y. Huang and M. Shieh,* Selenium─Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations,” Organometallics, 2010, 29, 4396-4405.
    14. M.Shieh,* C.-N. Lin, C.-Y. Miu, M.-H. Hsu, Y.-W. Pan and L.-F. Ho, “Chromium-Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C=O Activation of Acetone,” Inorg. Chem., 2010, 49, 8056-8066.
    15. M. Shieh,* C.-H. Ho,W.-S. Sheu* and H.-W. Chen, “Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium─Manganese Carbonyl Cluster [Se6Mn6(CO)18]4−,” J. Am. Chem. Soc., 2010, 132, 4032-4033.
    16. M. Shieh,* Y.-Y. Chu, C.-Y. Miu, P.-F. Wu and T.-M. Zeng, Bimetallic Ru-Cu Tellurido Complexes: Controlled Synthesis and Electrochemical Studies of Copper Halide-TeRu5 and Te2Ru4 Clusters,Dalton Trans., 2010, 39, 1492. (Selected as a Hot Article)
    17. B.-G. Chen, C.-H. Ho, C.-J. Lee and M. Shieh,* “Copper Halide-Incorporated Tellurium─Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations,” Inorg. Chem., 2009, 48, 10757-10768.
    18. M. Shieh,* C.-H. Ho, W.-S. Sheu,* B.-G. Chen, Y.-Y. Chu, C.-Y. Miu, H.-L. Liu and C.-C. Shen, “Semiconducting Tellurium–Iron–Copper Carbonyl Polymers,” J. Am. Chem. Soc., 2008, 130, 14114.
    19. M. Shieh,* C.-Y. Miu, C.-J. Lee, W.-C. Chen, Y.-Y. Chu and H.-L. Chen, “Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies,” Inorg. Chem., 2008, 47, 11018.
    20. M. Shieh,* M.-H. Hsu, W.-S. Sheu, L.-F. Jang, S.-F. Lin, Y.-Y. Chu, C.-Y. Miu, Y.-W. Lai, H.-L. Liu and J. L. Her, “Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of the Semiconducting Cluster Chain Polymer [{PPh4}2{Te2Ru4(CO)10Cu4Br2Cl2}·THF]¥,” Chem-Eur. J., 2007, 13, 6605.
    21. M. Shieh,* L.-F. Ho, P.-C. Chen, M.-H. Hsu, H.-L. Chen, Y.-W. Guo, Y.-W. Pan and Y.-C. Lin, “Reaction of [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations,” Organometallics, 2007, 26, 6184.
    22. M.-H. Hsu, R.-T. Chen, W.-S. Sheu and M. Shieh,* “Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem., 2006, 45, 6740.
    23. Y.-W. Lai, J.-J. Cherng, W.-S. Sheu, G.-A. Lee and M. Shieh,* “Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with Propargyl Bromide,” Organometallics, 2006, 25, 184.
    24. M. Shieh,* H.-S. Chen and Y.-W. Lai, “Reaction of the Tellurium-Capped Triiron Cluster [TeFe3(CO)9]2- with the Bifunctional Propargyl Bromide: Formation of a Series of Novel Organic Te-Fe-CO Complexes,” Organometallics, 2004, 23, 4018.
    25. M. Shieh,* S.-F. Lin, Y.-W. Guo, M.-H. Hsu and Y.-W. Lai, “New Strategy to Mixed-Group 6 Metal Carbonyl Telluride Complexes: Completion of the Trigonal Bipyramidal Clusters [Te2CrM2(CO)10]2- (M = Cr, Mo, W),” Organometallics, 2004, 23, 5182.
    26. M. Shieh,* R.-L. Chung, C.-H. Yu, M.-H Hsu, C.-H. Ho, S.-M. Peng and Y.-H. Liu, “The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se),Inorg. Chem., 2003, 42, 5477.
    27. M. Shieh,* L.-F. Ho, Y.-W. Guo, S.-F. Lin, Y.-C. Lin, S.-M. Peng and Y.-H. Liu, Carbonylchromium Monotelluride Complexes [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3): Two Important Intermediates,” Organometallics, 2003, 22, 5020.
    28. M. Shieh,* Y. Liou, M.-H. Hsu, R.-T. Chen, S.-J. Yeh, S.-M. Peng and G.-H. Lee, A Unique Bismuth-Iron Chain Polymer Containing the ...-Bi-Fe-... Link: Formation and Structure of [n-BuBiFe(CO)4]¥,Angew. Chem. Int. Ed. Engl., 2002, 41, 2384.
    29. M. Shieh,* J.-J. Cherng, Y.-W. Lai, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Derivatives of Bismuth: New Syntheses and Relevance to C-O Activation,Chem. Eur. J., 2002, 8, 4522.
    30. J.-J. Cherng, Y.-W. Lai, Y.-H. Liu, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis of Chromium Pentacarbonyl Dertives of Arsenic(V) and Antimony(V). Contrasting Chemical Reactivity with Organic Halogen Derivatives,” Inorg. Chem., 2001, 40, 1206.
    31. M. Shieh,* H.-S. Chen, H.-Y. Yang, S.-F. Lin and C.-H. Ueng, “Tellurium-Bridged Manganese Carbonyl Clusters: Synthesis and Structural Transformations of [Te4Mn3(CO)10]-, [Te2Mn3(CO)9]2-, [Te2Mn3(CO)9]-, and [Te2Mn4(CO)12]2-,” Chem. Eur. J., 2001, 7, 3152.
    32. M. Shieh,* L.-F. Ho, L.-F. Jang, C.-H. Ueng, S.-M. Peng and Y.-H. Liu, “First Selenium-Capped Carbonyltrichromium Complex [Se2Cr3(CO)10]2-: a Novel Cr3 Ring Cluster,” Chem. Commun., 2001, 1014.
    33. M. Shieh,* H.-S. Chen, H.-H Chi and C.-H. Ueng, “Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotation Isomers,” Inorg. Chem., 2000, 39, 5561.
    34. J.-J. Cherng, G.-H. Lee, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis and Characterization of a New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[H{Cr(CO)5}3]) (E = As, Sb),” Organometallics, 2000, 19, 213-215.
    35. M. Shieh,* H.-S. Chen, H.-Y. Yang and C.-H. Ueng, “[(TeMe2)Mn(CO)4(m5-Te)(m4-Te)Mn4(CO)12]-: A Pentacoordinate Bridging Tellurido Ligand in a Square- Pyramidal Geometry,” Angew. Chem., 1999, 111, 1339-1341; Angew. Chem. Int. Ed. Engl., 1999, 38, 1252-1254.
Unit Title Department Position Date
National Taiwan Normal UniversityDistinguished ProfessorDepartment of Chemistry 2011-02 ~
National Science Council ChemistryAdvisory Committee2009-01 ~ 2011-12
National Science Council Chemistry Research Promotion CenterAdvisory Committee2004-01 ~ 2005-12
National Taiwan Normal UniversityProfessorDepartment of ChemistryChairman2003-08 ~ 2006-07
Academia SinicaAdjunct Research FellowInstitute of Chemistry 2002-10 ~
National Science Council Inorganic DivisionPanel2000-01 ~ 2002-12
National Taiwan Normal UniversityProfessorDepartment of ChemistryProfessor1994-08 ~
National Taiwan Normal UniversityAssociate ProfessorDepartment of ChemistryAssociate Professor1989-08 ~ 1994-07
Texas A & M UniversityPostdoctoral Research AssociateDepartment of ChemistryResearch Associate1988-08 ~ 1989-07
National Taiwan Normal UniversityTeaching AssistantDepartment of ChemistryTeaching Assistant1982-08 ~ 1984-07
Academic Degrees
School Nation Department Degree Date
Rice UniversityU.S.ChemistryPh.D.1984-08 ~ 1988-06
National Taiwan Normal UniversityTaiwanChemistryB.S.1978-09 ~ 1982-06
Awarded Year Award Arwarding Unit
2015Distinguished professorNational Taiwan Normal University
2011Distinguished professorNational Taiwan Normal University
Off-campus ExcellenceOverview
Awarded Year Award Arwarding Unit
2000A-level National Science Council Research AwardNational Science Council
1999A-level National Science Council Research AwardNational Science Council
1998A-level National Science Council Research AwardNational Science Council
1997A-level National Science Council Research AwardNational Science Council
1996A-level National Science Council Research AwardNational Science Council
1995A-level National Science Council Research AwardNational Science Council
1994A-level National Science Council Research AwardNational Science Council
1993A-level National Science Council Research AwardNational Science Council
1991A-level National Science Council Research AwardNational Science Council
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  1. Journal papers
  2. Conference papers
  3. Research projects