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個人詳細資料

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˹ʹϤ
姓名 謝明惠
Office_Hour  
實驗室電話 (02)77346187; (02)77346188
辦公室電話 (02)77346118
傳真 (02)29309081
聯絡地址 (11677)台北市文山區汀州路四段88號
E-mail mshieh@ntnu.edu.tw
實驗室網頁 http://www.chem.ntnu.edu.tw/~MShieh/index.html
類別 專任師資
職稱 教授
研究領域 金屬簇化學、有機金屬、催化反應、計算化學
學術專長 奈米級金屬簇半導體之製成與光電特性研究。
金屬簇化合物活化小分子(例如:CO2、CO、O2、H2、MeOH)之反應探討。
新型金屬簇化合物的合成開發與其電化學及磁性的探討。
金屬簇化合物之有機催化反應。
DFT理論計算。
指導學生  
實驗室 奈米金屬簇研究室 /

學術著作

  1. 期刊論文
    1. M. Shieh,* C.-C. Yu, K.-J. Hsing and W.-J. Chang, “The Well-Defined Bismuth(III) in a Multiply Bonded Trigonal-Planar Complex with Prodigious Lewis Acidity,Chem.Eur. J., 2017, 23, 11677─11683.
    2. M. Shieh,* C.-C. Yu, C.-Y. Miu, C.-H. Kung, C.-Y. Huang, Y.-H. Liu, H.-L. Liu and C.-C. Shen, “Semiconducting Coordination Polymers Based on the Pre-Designed Ternary Te–Fe–Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers,Chem.Eur. J., 2017, 23, 11261─11271.
    3. M. Shieh,* C.-Y. Miu, Y.-H. Liu, Y.-Y. Chu, K.-J. Hsing, J.-I Chiu and C.-F. Lee, “Ternary Se─Ru─Cu Clusters: Facile Synthesis, Electrochemistry, and UV/Vis Absorption,” J. Organomet. Chem., 2016, 815816, 74─83.
    4. C.-N. Lin, C.-Y. Huang, C.-C. Yu, Y.-M. Chen, W.-M. Ke, G.-J. Wang, G.-A. Lee and M. Shieh,* “Iron Carbonyl Cluster-Incorporated Cu(I) NHC Complexes in Homocoupling of Arylboronic Acids: an Effective [TeFe3(CO)9]2− Ligand,Dalton Trans., 2015, 44, 16675─16679.
    5. M. Shieh,* C.-Y. Miu, K.-J. Hsing, L.-F. Jang and C.-N. Lin, “Copper-Incorporated Mono- and Di-TeRu5 Metal Carbonyl Complexes: Syntheses, Structures, and an Unusual Skeletal Arrangement,Dalton Trans., 2015, 44, 6526─6536.
    6. M. Shieh,* Y.-Y. Chu, L.-F. Jang and C.-H. Ho, “CO and CO2 Fixation by SeRuCO Hydride Clusters,” Inorg. Chem., 2014, 53, 4284─4286.
    7. C.-N. Lin, W.-T. Jhu and M. Shieh,* “Vapochemically and Mechanochemically Reversible Polymerization/Depolymerization of SFeCu Carbonyl Clusters,“ Chem. Commun., 2014, 50, 1134-1136.
    8. M. Shieh,* C.-H. Yu, Y.-Y. Chu, Y.-W. Guo, C.-Y. Huang, K.-J. Hsing, P.-C. Chen and C.-F. Lee, “Trigonal Bipyramidal and Square Pyramidal ChromiumManganese Chalcogenide Clusters [E2CrMn2(CO)n]2 (E = S, Se, Te; n = 9, 10): Synthesis, Electrochemistry, UV/Vis Absorption, and Computational Studies,” Chem. Asian J., 2013, 8, 963-973.
    9. M. Shieh,* C.-Y. Huang, C.-J. Lee,K.-J. Hsing, Y.-W. Li, Y.-Y. Chu and W.-T. Jhu, “Controlled Synthesis of Copper Halide-IncorporatedTriiron Carbonyl Sulfide Clusters: Synthesis, Electrochemistry, and Computational Studies,” Polyhedron, 2013, 52, 879-889.
    10. M. Shieh,* C.-Y. Miu, Y.-Y. Chu and C.-N. Lin, “Recent Progress in the Chemistry of Anionic Groups 6─8 Carbonyl Chalcogenide Clusters,” Coord. Chem. Rev., 2012, 256, 637-694.
    11. M. Shieh,* C.-Y. Miu, K.-C. Huang, C-F. Lee and B.-G. Chen, “Stepwise Construction of MangneseChromium Carbonyl Chalcogenide Complexes: Synthesis, Electrochemical Properties, and Computational Studies, ” Inorg. Chem., 2011, 50, 7735-7748.
    12. M. Shieh,* Y.-Y. Chu, M.-H. Hsu, W.-M. Ke and C.-N. Lin, “Lead-Chromium Carbonyl Complexes Incorporated with Group 8 Metals: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem., 2011, 50, 565-575.
    13. C.-H. Ho, Y.-Y. Chu, C.-N. Lin, H.-W. Chen, C.-Y. Huang and M. Shieh,* Selenium─Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations,” Organometallics, 2010, 29, 4396-4405.
    14. M.Shieh,* C.-N. Lin, C.-Y. Miu, M.-H. Hsu, Y.-W. Pan and L.-F. Ho, “Chromium-Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C=O Activation of Acetone,” Inorg. Chem., 2010, 49, 8056-8066.
    15. M. Shieh,* C.-H. Ho,W.-S. Sheu* and H.-W. Chen, “Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium─Manganese Carbonyl Cluster [Se6Mn6(CO)18]4−,” J. Am. Chem. Soc., 2010, 132, 4032-4033.
    16. M. Shieh,* Y.-Y. Chu, C.-Y. Miu, P.-F. Wu and T.-M. Zeng, Bimetallic Ru-Cu Tellurido Complexes: Controlled Synthesis and Electrochemical Studies of Copper Halide-TeRu5 and Te2Ru4 Clusters,Dalton Trans., 2010, 39, 1492. (Selected as a Hot Article)
    17. B.-G. Chen, C.-H. Ho, C.-J. Lee and M. Shieh,* “Copper Halide-Incorporated Tellurium─Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations,” Inorg. Chem., 2009, 48, 10757-10768.
    18. M. Shieh,* C.-H. Ho, W.-S. Sheu,* B.-G. Chen, Y.-Y. Chu, C.-Y. Miu, H.-L. Liu and C.-C. Shen, “Semiconducting Tellurium–Iron–Copper Carbonyl Polymers,” J. Am. Chem. Soc., 2008, 130, 14114.
    19. M. Shieh,* C.-Y. Miu, C.-J. Lee, W.-C. Chen, Y.-Y. Chu and H.-L. Chen, “Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies,” Inorg. Chem., 2008, 47, 11018.
    20. M. Shieh,* M.-H. Hsu, W.-S. Sheu, L.-F. Jang, S.-F. Lin, Y.-Y. Chu, C.-Y. Miu, Y.-W. Lai, H.-L. Liu and J. L. Her, “Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of the Semiconducting Cluster Chain Polymer [{PPh4}2{Te2Ru4(CO)10Cu4Br2Cl2}·THF]¥,” Chem-Eur. J., 2007, 13, 6605.
    21. M. Shieh,* L.-F. Ho, P.-C. Chen, M.-H. Hsu, H.-L. Chen, Y.-W. Guo, Y.-W. Pan and Y.-C. Lin, “Reaction of [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations,” Organometallics, 2007, 26, 6184.
    22. M.-H. Hsu, R.-T. Chen, W.-S. Sheu and M. Shieh,* “Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem., 2006, 45, 6740.
    23. Y.-W. Lai, J.-J. Cherng, W.-S. Sheu, G.-A. Lee and M. Shieh,* “Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with Propargyl Bromide,” Organometallics, 2006, 25, 184.
    24. M. Shieh,* H.-S. Chen and Y.-W. Lai, “Reaction of the Tellurium-Capped Triiron Cluster [TeFe3(CO)9]2- with the Bifunctional Propargyl Bromide: Formation of a Series of Novel Organic Te-Fe-CO Complexes,” Organometallics, 2004, 23, 4018.
    25. M. Shieh,* S.-F. Lin, Y.-W. Guo, M.-H. Hsu and Y.-W. Lai, “New Strategy to Mixed-Group 6 Metal Carbonyl Telluride Complexes: Completion of the Trigonal Bipyramidal Clusters [Te2CrM2(CO)10]2- (M = Cr, Mo, W),” Organometallics, 2004, 23, 5182.
    26. M. Shieh,* R.-L. Chung, C.-H. Yu, M.-H Hsu, C.-H. Ho, S.-M. Peng and Y.-H. Liu, “The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se),Inorg. Chem., 2003, 42, 5477.
    27. M. Shieh,* L.-F. Ho, Y.-W. Guo, S.-F. Lin, Y.-C. Lin, S.-M. Peng and Y.-H. Liu, Carbonylchromium Monotelluride Complexes [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3): Two Important Intermediates,” Organometallics, 2003, 22, 5020.
    28. M. Shieh,* Y. Liou, M.-H. Hsu, R.-T. Chen, S.-J. Yeh, S.-M. Peng and G.-H. Lee, A Unique Bismuth-Iron Chain Polymer Containing the ...-Bi-Fe-... Link: Formation and Structure of [n-BuBiFe(CO)4]¥,Angew. Chem. Int. Ed. Engl., 2002, 41, 2384.
    29. M. Shieh,* J.-J. Cherng, Y.-W. Lai, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Derivatives of Bismuth: New Syntheses and Relevance to C-O Activation,Chem. Eur. J., 2002, 8, 4522.
    30. J.-J. Cherng, Y.-W. Lai, Y.-H. Liu, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis of Chromium Pentacarbonyl Dertives of Arsenic(V) and Antimony(V). Contrasting Chemical Reactivity with Organic Halogen Derivatives,” Inorg. Chem., 2001, 40, 1206.
    31. M. Shieh,* H.-S. Chen, H.-Y. Yang, S.-F. Lin and C.-H. Ueng, “Tellurium-Bridged Manganese Carbonyl Clusters: Synthesis and Structural Transformations of [Te4Mn3(CO)10]-, [Te2Mn3(CO)9]2-, [Te2Mn3(CO)9]-, and [Te2Mn4(CO)12]2-,” Chem. Eur. J., 2001, 7, 3152.
    32. M. Shieh,* L.-F. Ho, L.-F. Jang, C.-H. Ueng, S.-M. Peng and Y.-H. Liu, “First Selenium-Capped Carbonyltrichromium Complex [Se2Cr3(CO)10]2-: a Novel Cr3 Ring Cluster,” Chem. Commun., 2001, 1014.
    33. M. Shieh,* H.-S. Chen, H.-H Chi and C.-H. Ueng, “Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotation Isomers,” Inorg. Chem., 2000, 39, 5561.
    34. J.-J. Cherng, G.-H. Lee, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis and Characterization of a New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[H{Cr(CO)5}3]) (E = As, Sb),” Organometallics, 2000, 19, 213-215.
    35. M. Shieh,* H.-S. Chen, H.-Y. Yang and C.-H. Ueng, “[(TeMe2)Mn(CO)4(m5-Te)(m4-Te)Mn4(CO)12]-: A Pentacoordinate Bridging Tellurido Ligand in a Square- Pyramidal Geometry,” Angew. Chem., 1999, 111, 1339-1341; Angew. Chem. Int. Ed. Engl., 1999, 38, 1252-1254.
經歷一覽
服務機關 職稱 部門/系所 擔任職務 起迄年月
科技部自然司 貴儀學門複審委員2013年01月 ~ 2015年12月
國立臺灣師範大學特聘教授化學系 2011年02月 ~
國科會自然處 化學學門諮議委員2009年01月 ~ 2011年12月
國科會自然處 化學研究推動中心審議委員2004年01月 ~ 2005年12月
國立臺灣師範大學教授化學系主任2003年08月 ~ 2006年07月
中央研究院合聘研究員化學所 2002年10月 ~
國科會自然處 化學學門審議委員2000年01月 ~ 2002年12月
國立臺灣師範大學教授化學系 1994年08月 ~
國立臺灣師範大學副教授化學系 1989年08月 ~ 1994年07月
美國德州農工大學博士後研究化學系研究員1988年08月 ~ 1989年07月
國立臺灣師範大學助教化學系 1982年08月 ~ 1984年07月
學歷一覽
學校名稱 國別 系所 學位 起迄年月
萊斯大學美國化學系博士1984年08月 ~ 1988年06月
國立臺灣師範大學臺灣化學系理學士1978年09月 ~ 1982年06月
校內榮譽一覽
得獎年度 獎項名稱 頒獎單位
2015特聘教授國立台灣師範大學
2011特聘教授國立台灣師範大學
2009國立台灣師範大學理學院學術優良教師補助國立台灣師範大學理學院
2008國立台灣師範大學理學院學術優良教師補助國立台灣師範大學理學院
2007國立台灣師範大學理學院學術優良教師補助國立台灣師範大學理學院
2006國立台灣師範大學研究績優獎國立台灣師範大學
2005國立台灣師範大學研究績優獎國立台灣師範大學
2005國立台灣師範大學理學院學術優良教師補助國立台灣師範大學理學院
校外榮譽一覽
得獎年度 獎項名稱 頒獎單位
2000國科會甲等獎國科會
1999國科會甲等獎國科會
1998國科會甲等獎國科會
1997國科會甲等獎國科會
1996國科會甲等獎國科會
1995國科會甲等獎國科會
1994國科會甲等獎國科會
1993國科會甲等獎國科會
1991國科會甲等獎國科會
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  1. 期刊論文
  2. 研討會論文
  3. 學術研究計畫
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