李位仁
姓名 李位仁
电子邮件
联络电话 (02)77496133
网站 http://140.122.142.231/~wzlee/
实验室电话 (02)77496186
职称 研究讲座教授
研究领域 生物无机、仿生催化、有机金属
学术专长 研究兴趣 (1)含金属酵素之活性中心的小分子模型之合成与特性研究及光谱探讨和模型与酵素间之比较，以期更了酵素催化反应之反应机制。 (2)合成仿生催化剂之金属错合物，以进行碳氢化合物之氧合催化反应。
指导学生 柯名时 / 张智凯 / 杨人翰 / 杨咏剀 / 蔡杰纮 / 陈志铭 / 朱允立 / 林宗翰 / 王维铃 / 陈许志勇
实验室 生物无机研究室
  1. T. Chatterjee, B. Molnar, W.-Z. Lee,* K. V. Lakshmi,* and M. Ravikanth* “Calixsmaragdyrin: A Versatile Ligand for Coordination Complexes” Inorg. Chem. 2017, 56, 3763-3772.
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  2. J.-H. Fang, J.-H. Jian, H.-C. Chang, T.-S. Kuo, W.-Z. Lee, P.-Y. Wu, and H.-Liang Wu* "Synthesis of Quaternary-Carbon-Containing β2,2-Amino Acids by the RhI-Catalyzed Enantioselective Arylation of α-Substituted β-Nitroacrylates" Chem. Eur. J. 2017, 23, 1830-1838.
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  3. C.-C. Wang, H.-C. Chang, Y.-C. Lai, H. Fang, C.-C. Li, H.-K. Hsu, Z.-Y. Li, T.-S. Lin, T.-S. Kuo, F. Neese, S. Ye,* Y.-W. Chiang,* M.-L. Tsai,* W.-F. Liaw,* and W.-Z. Lee* “A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from its Superoxo Intermediate via Hydrogen Atom Abstraction” J. Am. Chem. Soc. 2016, 138, 14186-14189.
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  4. T. Kaur, W.-Z. Lee and M. Ravikanth* “Rhenium(I) Tricarbonyl Complexes of meso-Tetraaryl-21,23-diheteroporphyrins” Inorg. Chem. 2016, 55, 5305-5311.
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  5. H. D. Stout, S. T. Kleespies, C.-W. Chiang, W.-Z. Lee, L. Que, Jr., E. Münck,* and E. L. Bominaar* “Spectroscopic and Theoretical Study of Spin-Dependent Electron Transfer in an Iron(III) Superoxo Complex” Inorg. Chem. 2016, 55, 5215-5226.
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  6. T. Kaur, W.-Z. Lee and M. Ravikanth* “N-Methylated 25-Oxasmaragdyrins: Synthesis, Structure and Properties” J. Porphyr. Phthalocyanines 2016, 20, 582-589.
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  7. T. Chatterjee, W.-Z. Lee and M. Ravikanth* “Stabilization of Hexa-Coordinated P(V) Corroles by Axial Silyloxy Groups” Dalton. Trans. 2016, 45, 7815-7822.
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  8. C.-C. Chou,* C.-C. Yang, H.-C. Chang, W.-Z. Lee* and T.-S. Kuo “Weaving an infinite 3-D supramolecular network via AuI⋯AuIII aurophilicity and C-H⋯Cl hydrogen bonding” New J. Chem. 2016, 40, 1944-1947.
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  9. H.-C. Chang, Y.-C. Hsu, C.-H. Chen, T.-S. Kuo and W.-Z. Lee* “Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)–(2-mercaptophenyl)phosphine complexations” Dalton Trans. 2015, 44, 20808-20811.
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  10. R. Sharma, W.-Z. Lee, and M. Ravikanth* “Formation of Unusual Dithiaphlorins from Condensation of 2,5-bis(Arylhydroxymethyl)thiophene and Pyrrole” RSC Adv. 2015, 5, 102765-102771.
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  11. H. Kalita, W.-Z. Lee, G.-G. Theophall, K.-V. Lakshmi, and M. Ravikanth* “A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle” Chem. Eur. J. 2015, 21, 11315-11319.
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  12. E. Ganapathi, T Chatterjee, W.-Z. Lee and M. Ravikanth* “Synthesis, Structure, and Properties of Core-modified Pentaphyrins Containing Six mesoCarbons” Asian J. Org. Chem. 2015, 4, 638-645.
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  13. H.-C. Chang, F.-C. Lo, W.-C. Liu, T.-H. Lin, W.-F. Liaw, T.-S. Kuo, and W.-Z. Lee* “Ambient Stable Trigonal Bipyramidal Copper(III) Complexes Equipped with an Exchangeable Axial Ligand” Inorg. Chem. 2015, 54, 5527-5533.
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  14. Y. Meesala, V. Kavala, H.-C. Chang, T.-S. Kuo, C.-F. Yao,* and W.-Z. Lee* “Anilido-Benzoxazole Boron Difluoride (ABB) Complexes: Novel bright fluorescent dyes in solution and in the solid state” Dalton Trans. 2015, 44, 1120-1129.
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  15. V. Lakshmi, W.-Z. Lee, and M. Ravikanth* "Synthesis, structure and spectral and electrochemical properties of 3-pyrrolyl BODIPY-metal dipyrrin complexes" Dalton Trans. 2014, 43, 16006-16014.
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  16. E. Ganapathi, W.-Z. Lee,* and M. Ravikanth* "Stable Nonaromatic [20]Dithiaporphyrin (2.1.1.1) Macrocycles: Synthesis, Structure, Spectral, Electrochemical and Metal Ion Sensing Studies” J. Org. Chem. 2014, 79, 9603-9612.
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  17. Y. Meesala, H.-L. Wu, B. Koteswararao, T.-S. Kuo, and W.-Z. Lee* “Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Hexanuclear Bis(μ-hydroxo)Copper(II) Catalyst” Organometallics 2014, 33, 4385-4393.
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  18. H. Kalita, W.-Z. Lee, and M. Ravikanth* "Phosphorus Complexes of meso-Triaryl-25-oxasmaragdyrins" Inorg. Chem. 2014, 53, 9431-9438.
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  19. H. Kalita, D. Kalita, W.-Z. Lee, J. Bellare, and M. Ravikanth* “Synthesis of meso-Pyrrole-Substituted 22-Oxacorroles by a "3+2" Approach” Chem. Eur. J. 2014, 20, 10404-10413.
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  20. C.-W. Chiang, S. Kleespies, H. Stout, K. Meier, P.-Y. Li, E. Bominaar,* L. Que, Jr.,* E. Münck,* and W.-Z. Lee* “Characterization of a Paramagnetic Mononuclear Nonheme Iron-Superoxo Complex” J. Am. Chem. Soc. 2014, 136, 10846-10849.
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  21. T. Kaur, W.-Z. Lee, and M. Ravikanth* "N-Methyl-21-thiaprophyrins" Eur. J. Org. Chem. 2014, 2261-2267.
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  22. C.-W. Chiang, Y.-L. Chu, H.-L. Chen, T.-S. Kuo, and W.-Z. Lee* “Synthesis and Characterization of NiIIIN3S2 Complexes as Active Site Models for the Oxidized Form of Nickel Superoxide Dismutase” Chem. Eur. J. 2014, 20, 6283-6286.
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  23. E. Ganapathi, W.-Z. Lee* and M. Ravikanth* “Synthesis, Structure, Spectral and Electrochemical Properties of Meso-Tetraaryl 27-Thiasapphyrins” Asian J. Org. Chem. 2014, 3, 290-296.
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  24. B. Gopula, C.-W. Chiang, W.-Z. Lee, T.-S. Kuo, P.-Y. Wu, J. P. Henschke, and H.-Liang Wu* "Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to N-Tosyl Imines" Org. Lett. 2014, 16, 632-635.
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  25. H. Kalita, W.-Z. Lee, and M. Ravikanth,* “Synthesis, structure, spectral and electrochemical properties of B(OR)2-smaragdyrin complexes” Dalton Trans. 2013, 42, 14537-14544.
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  26. A. Ghosh, W.-Z. Lee, and M. Ravikanth* "Unusual formation of thiaisoporphyrins from 21-thiaporphyrins" Chem. Commun. 2013, 49, 8677-8679.
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  27. H. Kalita, W.-Z. Lee, and M. Ravikanth* "Synthesis and Functionalization of BF2-complexes of meso-free 25-oxasmaragdyrin” J. Org. Chem. 2013, 78, 6285-6290.
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  28. A. Ghosh, T. Chatterjee, W.-Z. Lee, and M. Ravikanth* "Unusual Formation of 21-Oxacorrole from 21-Oxaporphyrin Induced by Phosphoryl Chloride" Org. Lett. 2013, 15, 1040-1043.
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  29. W.-Z. Lee,* C.-W. Chiang, G. M. Kulkarni, and T.-S. Kuo “Highly Efficient Proline Ester-Based Catalysts for Michael Addition of Thiophenols to α,β-Enones” J. Chin. Chem. Soc. 2013, 60, 245-250.
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  30. B. Gopula, W.-Z. Lee, H.-L. Wu* “Preparation of Chiral α-Substituted Alaninates through an Efficient Diastereoselective Synthesis of Trisubstituted Allylic Alcohols” Chem. Asian J. 2013, 8, 80-83.
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  31. A. Ghosh, W.-Z. Lee, and M. Ravikanth* "Synthesis, Structure and Properties of a Five-Coordinate Oxophosphorus(V) meso-Triphenylcorrole" Eur. J. Inorg. Chem. 2012, 4231-4239.
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  32. W.-Z. Lee,* T.-L. Wang, H.-C. Chang, Y.-T. Chen, and T.-S. Kuo “A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition” Organometallics 2012, 31, 4106-4109.
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  33. W.-Z. Lee,* C.-W. Chiang, T.-H. Lin, and T.-S. Kuo “A Discrete Five-Coordinate NiIII Complex Resembling the Active Site of the Oxidized Form of Nickel Superoxide Dismutase” Chem. Eur. J. 2012, 18, 50-53.
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  34. W.-Z. Lee,* H.-S. Tsang, T.-L. Wang, H.-L. Tsai,* and T.-S. Kuo “Bio-inspired Catalytic Conjugate Additions of Thiophenols to α,β-Enones by a Disubstituted Benzoate-Bridged Nickel Mimic for the Active Site of Urease” Organometallics 2010, 29, 2874-2881.
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  35. W.-Z. Lee,* T.-L. Wang, H.-S. Tsang, C.-Y. Liu, and C.-T. Chen,* T.-S. Kuo “Temperature Dependant Nuclearity in bis(Benzimidazoyl) Nickel Complexes and Their Catalysis Towards Conjugate Addition of Thiophenols to α,β-Enones” Organometallics 2009, 28, 652-655.
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  36. W.-Z. Lee,* Y.-L. Kang, T.-L. Wang, C.-C. Su,* and T.-S. Kuo “Structural Interconversion Controlled by Hydrogen-bond Interactions: A Mononuclear Copper Triamine Complex and A polynuclear Copper Triamine Sheet” Cryst. Growth Des. 2008, 8, 2614-2616.
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  37. W.-Z. Lee,* H.-S. Tseng, M.-Y. Ku, and T.-S. Kuo, “Dinickel Complexes of Disubstituted Benzoate Polydentate Ligands: Mimics for the Active Site of Urease” Dalton Trans. 2008, 2538-2541.
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  38. C.-T. Chen,* S. Bettigeri, S.-S. Weng, V. Pawar, Y.-H. Lin, C.-Y. Liu, W.-Z. Lee,* “Asymmetric Aerobic Oxidation of alpha-Hydroxy Acid Derivatives by C4-Symmetric, Vanadate-centered, Tetrakisvanadyl(V) Clusters Derived from N-Salicylidene-alpha-aminocarboxylates” J. Org. Chem. 2007, 72, 8175-8185.
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  39. W.-Z. Lee,* H.-S. Tseng, and T.-S. Kuo, “Ligand-Controlled Nuclearity in Nickel bis(Benzimidazolyl) Complexes” Dalton Trans. 2007, 2563-2570.
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  40. C.-H. Hung,* W.-M. Ching, G.-F. Chang, C.-H. Chuang, H.-W. Chu, and W.-Z. Lee, “Formation of a Sulfur-Atom-Inserted N-Confused Porphyrin Iron Nitrosyl Complex by Denitrosation and C-S Bond Cleavage of an S-Nitrosothiol” Inorg. Chem. 2007, 46, 10941-10943.
     
  41. D. J. Darensbourg, W.-Z. Lee, and L. P. Andrea, “The Synthesis and Characterization of iron cyanide building blocks: [K]2[CpFe(CN)3] and its pentamethylcyclopentadienyl (Cp*) analog” Inorg. Chim. Acta 2005, 358, 4095-4098.
     
  42. D. J. Darensbourg, W.-Z. Lee, and M. J. Adams, “Phosphine Derivatives of Diamond-Shaped Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups” Inorganic Syntheses 2004, 34, 172-177.
     
  43. D. J. Darensbourg,; W.-Z. Lee, A. L. Phelps, and E. Guidry, “Kinetic Study of the Insertion and Deinsertion of Carbon Dioxide into fac-(CO)3(dppe)MnOR Derivatives” Organometallics 2003, 22, 5585-5588.
     
  44. W.-Z. Lee and W. B. Tolman, “Toward Synthetic Analogs of Linked Redox and Catalytic Multimetal Site in Proteins: A Model of the Histidine-Cysteine Bridged Dicopper Array” Inorg. Chem. 2002, 41, 5656-5658.
     
  45. D. J. Darensbourg, W.-Z. Lee, and J. C. Yarbrough, “Synthesis and Characterization of a Monocyanide-Bridged Bimetallic Iron(II) and Copper(I) Complex” Inorg. Chem. 2001, 40, 6533-6536.
     
  46. D. J. Darensbourg, W.-Z. Lee, M. J. Adams, and J. C. Yarbrough, “Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups Containing Monodentate or Bidentate Phosphanes Bound to Copper(I), Including an Alternative Structure Based on the Nature of the Bidentate Phosphane Ligand” Euro. J. Inorg. Chem. 2001, 2001, 2811-2822.
     
  47. D. J. Darensbourg, W.-Z. Lee, M. J. Adams, D. L. Larkins, and J. H. Reibenspies, “Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups” Inorg. Chem. 1999, 38, 1378-1379.
     
  48. C.-H. Lai, W.-Z. Lee, M. L. Miller, D. J. Darensbourg, and M. Y. Darensbourg, “Responses of the Fe(CN)2(CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase” J. Am. Chem. Soc. 1998, 120, 10103-10114.
     
  49. D. J. Darensbourg, J. H. Reibenspies, C.-H. Lai, W.-Z. Lee, and M. Y. Darensbourg, “Analysis of an Organometallic Iron Site model for the Heterodimetallic Unit of [NiFe]Hydrogenase” J. Am. Chem. Soc. 1997, 119, 7903-7904.
年度 论文名称
2022 Hydrogen Atom Transfer Thermodynamics of Homologous Co(III)- and Mn(III)-Superoxo Complexes: The Effect of the Metal Spin State, JACS Au, vol. 2, Aug. 2022
2022 Investigation of optimal conditions needed for the production of indigo and subsequent dyeing using CO2/O2 sensors and a cellphone camera, Analytical Sciences, vol. 38, May. 2022
2020 Ambiphilicity of a Mononuclear Cobalt(III) Superoxo Complex, Chem. Commun., vol. 56, Dec. 2020
2020 Redox reactions between chromium(VI) and hydroquinone: Alternative pathways for polymerization of organic molecules, Environmental Pollution, vol. 261, Jun. 2020
2020 A Manganese(IV)-Hydroperoxo Intermediate Generated by Protonation of the Corresponding Manganese(III)-Superoxo Complex, J. Am. Chem. Soc., vol. 142, Jun. 2020
2020 Insights into the chemistry and structure of iron gall ink based on “two-step” bamboo nib-spray/mass spectrometry, International Journal of Mass Spectrometry, vol. 451, May. 2020
2020 Dinitrosyliron Complex [(PMDTA)Fe(NO)2]: Intermediate for Nitric Oxide Monooxygenation Activity in Nonheme Iron Complex, Inorganic Chemistry, vol. 59, May. 2020
2019 Hydrogen Bond-Enabled Heterolytic and Homolytic Peroxide Activation within Nonheme Copper(II)-Alkylperoxo Complexes, Inorg. Chem., vol. 58, Sep. 2019
2019 Conversion of a Fleeting Open-Shell Iron Nitride into an Iron Nitrosyl, Angew. Chem. Int. Ed., vol. 58, Sep. 2019
2019 Mononuclear Manganese(III) Superoxo Complexes: Synthesis, Characterization, and Reactivity, Inorg. Chem., vol. 58, Aug. 2019
2019 Ambient Stable Cyanomethylcopper(III) Complex: A Strong Cu-Csp 3 Bond Supported by a PS3-Tripodal Chelator, Inorg. Chem., vol. 58, Jan. 2019
2018 Synthesis, Structural, Spectral, and Electrochemical Studies of Selenabenziporphyrin and Its Pd(II) Complex, Inorg. Chem., vol. 57, Aug. 2018
2018 Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex, Org. Lett., vol. 30, Mar. 2018
2018 Nickel(III)-mediated oxidative cascades from a thiol-bearing nickel(II) precursor to the nickel(IV) product, Dalton Transactions, vol. 47, Jan. 2018
2017 Construction of Novel Cyclic Tetrads by Axial Coordination of Thiaporphyrins to Tin(IV) Porphyrin, Inorg. Chem., vol. 56, Nov. 2017
2017 Hybrid Macrocycles of Subporphyrins and Triphyrins, Org. Lett., vol. 19, Nov. 2017
2017 Synthetic nickel-containing superoxide dismutase attenuates para-phenylenediamine-induced bladder dysfunction in rats, Oncotarget, vol. 21, Nov. 2017
2017 Synthesis of Quaternary-Carbon-Containing β2,2-Amino Acids by the RhI-Catalyzed Enantioselective Arylation of α-Substituted β-Nitroacrylates, Chem. Eur. J., vol. 23, Oct. 2017
2017 Calixsmaragdyrin: A Versatile Ligand for Coordination Complexes, Inorg. Chem., vol. 56, Apr. 2017
2016 A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from its Superoxo Intermediate via Hydro-gen Atom Abstraction, J. Am. Chem. Soc., vol. 138, Nov. 2016
2016 Rhenium(I) Tricarbonyl Complexes of meso-Tetraaryl-21,23-diheteroporphyrins, Inorg. Chem., vol. 55, Jun. 2016
2016 Spectroscopic and Theoretical Study of Spin-Dependent Electron Transfer in an Iron(III) Superoxo Complex, Inorg. Chem., vol. 55, Jun. 2016
2016 N-methylated 25-oxasmaragdyrins: Synthesis, structure and properties, J. Porphyrins Phthalocyanines, vol. 20, May. 2016
2016 Stabilization of hexa-coordinated P(V) corroles by axial silyloxy groups, Dalton Transactions, vol. 45, Mar. 2016
2016 Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid, Chem. Eur. J., vol. 22, Feb. 2016
2016 Weaving an infinite 3-D supramolecular network via AuI⋅⋅⋅AuIII aurophilicity and C-H⋅⋅⋅Cl hydrogen bonding, New. J. Chem., vol. 40, Jan. 2016
2015 Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole, RSC Advances, vol. 5, Dec. 2015
2015 Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)–(2-mercaptophenyl)phosphine complexation, Dalton Trans., vol. 44, Dec. 2015
2015 A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle, Chem. Eur. J., vol. 21, Aug. 2015
2015 Synthesis, Structure, and Properties of Core-modified Pentaphyrins Containing Six mesoCarbons, Asian. J. Org. Chem., vol. 2015, Jul. 2015
2015 Ambient Stable Trigonal Bipyramidal Copper(III) Complexes Equipped with an Exchangeable Axial Ligand, Inorg. Chem., vol. 54, May. 2015
2014 Synthesis, structures and electrochemical and photophysical properties of anilido-benzoxazole boron difluoride (ABB) complexes, Dalton Trans., vol. 44, Nov. 2014
2014 Synthesis, structure and spectral and electrochemical properties of 3-pyrrolyl BODIPY-metal dipyrrin complexes, Dalton Trans., vol. 43, Nov. 2014
2014 Stable Nonaromatic [20]Dithiaporphyrin (2.1.1.1) Macrocycles: Synthesis, Structure, Spectral, Electrochemical and Metal Ion Sensing Studies, J. Org. Chem., vol. 79, Oct. 2014
2014 Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Hexanuclear Bis(μ-hydroxo)Copper(II) Catalyst, Organometallics, vol. 33, Sep. 2014
2014 Phosphorus Complexes of meso-Triaryl-25-oxasmaragdyrins, Inorg. Chem., vol. 53, Sep. 2014
2014 Synthesis of meso-Pyrrole-Substituted 22-Oxacorroles by a "3+2" Approach, Chem. Eur. J., vol. 20, Aug. 2014
2014 Characterization of a Paramagnetic Mononuclear Nonheme Iron-Superoxo Complex, J. Am. Chem. Soc., vol. 136, Jul. 2014
2014 N-Methyl-21-thiaprophyrins, Eur. J. Org. Chem., vol. 2014, Jun. 2014
2014 Synthesis and Characterization of NiIIIN3S2 Complexes as Active Site Models for the Oxidized Form of Nickel Superoxide Dismutase, Chem. Eur. J., vol. 20, May. 2014
2014 Synthesis, Structure, Spectral and Electrochemical Properties of Meso-Tetraaryl 27-Thiasapphyrins, Asian. J. Org. Chem., vol. 3, Mar. 2014
2014 Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to N-Tosyl Imines, Org. Lett., vol. 16, Jan. 2014
2013 Synthesis, structure, spectral and electrochemical properties of B(OR)2-smaragdyrin complexes, Dalton Trans., vol. 42, Oct. 2013
2013 Unusual formation of thiaisoporphyrins from 21-thiaporphyrins, Chem. Commun., vol. 49, Oct. 2013
2013 Synthesis and Functionalization of BF2-complexes of meso-free 25-oxasmaragdyrin, J. Org. Chem., vol. 78, Jun. 2013
2013 Unusual Formation of 21-Oxacorrole from 21-Oxaporphyrin Induced by Phosphoryl Chloride, Org. Lett., vol. 15, Mar. 2013
2013 Highly Efficient Proline Ester-Based Catalysts for Michael Addition of Thiophenols to α,β-Enones, J. Chin. Chem. Soc., vol. 60, Mar. 2013
2013 Preparation of Chiral α-Substituted Alaninates through an Efficient Diastereoselective Synthesis of Trisubstituted Allylic Alcohols, Chem. Asian J., vol. 8, Jan. 2013
2012 Synthesis, Structure and Properties of a Five-Coordinate Oxophosphorus(V) meso-Triphenylcorrole, Eur. J. Inorg. Chem., vol. 2012, Sep. 2012
2012 A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition, Organometallics, vol. 31, May. 2012
2012 A Discrete Five-Coordinate NiIII Complex Resembling the Active Site of the Oxidized Form of Nickel Superoxide Dismutase, Chem. Eur. J., vol. 18, Jan. 2012
2010 Bio-inspired Catalytic Conjugate Additions of Thiophenols to ,-Enones by a Disubstituted Benzoate-Bridged Nickel Mimic for the Active Site of Urease, Organometallics, vol. 29, Jun. 2010
2009 Urease and Its Synthetic Mimics, Chemistry, vol. 67, Jun. 2009
2009 Temperature Dependant Nuclearity in bis(Benzimidazoyl) Nickel Complexes and Their Catalysis Towards Conjugate Addition of Thiophenols to α,β-Enones, Organometallics, vol. 28, Jan. 2009
2008 Dinickel Complexes of Disubstituted Benzoate Polydentate Ligands: Mimics for the Active Site of Urease, Dalton Trans., Mar. 2008
2008 Structural Interconversion Controlled by Hydrogen-bond Interactions: A Mononuclear Copper Triamine Complex and A polynuclear Copper Triamine Sheet, Cryst. Growth Des., vol. 8, Jan. 2008
2007 Formation of a Sulfur-Atom-Inserted N-Confused Porphyrin Iron Nitrosyl Complex by Denitrosation and C-S Bond Cleavage of an S-Nitrosothiol, Inorg. Chem., vol. 46, Nov. 2007
2007 Asymmetric Aerobic Oxidation of alpha-Hydroxy Acid Derivatives by C4-Symmetric, Vanadate-centered, Tetrakisvanadyl(V) Clusters Derived from N-Salicylidene-alpha-aminocarboxylates, J. Org. Chem., vol. 72, Apr. 2007
2007 Ligand-Controlled Nuclearity in Nickel Bis(benzimidazolyl)Complexes, Dalton Trans., Apr. 2007
年度 论文名称
2012 Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia- Michael Addition, The 6th Asian Biological Inorganic Chemistry Symposium, Nov. 05-08, 2012, Hong Kong
2012 Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia- Michael Addition, The 6th Asian Biological Inorganic Chemistry Symposium 第六届亚洲生物无机研讨会, Nov. 04-08, 2012, Hong Kong
2011 Nickel Functional Mimics with a Polydentate N/O Ligand for Nickel-Containing Superoxide Dismutase (NiSOD), 15th International Conference on Biological Inorganic Chemistry, Aug. 07-12, 2011, Vanouver, Canada
2010 A Discrete Five-Coordinate Ni(III) Complex: a Functional Model for the Oxidized Form of Nickel Superoxide Dismutase, The 5th Asian Biological Inorganic Chemistry Symposium, Nov. 01-05, 2010, Kaohsiung, Taiwan
2009 Nickel Biomimetics for the Active Site of Urease and their Catalysis towards the Conjugate Addition of Thiols to alpha,beta-Enones, 14th International Conference on Biological Inorganic Chemistry, Jul. 25-30, 2009, Nagoya, Japan
2008 Dinickel Complexes of Disubstituted Benzoate Polydentate Ligands: Mimics for the Active Site of Urease, The 4th Asian Biological Inorganic Chemistry Symposium, Nov. 10-13, 2008, Jeju, Korea
2006 Syntheses and Structures of Benzimidazole Nickel Complexes: Relevance to the Active Site of Urease, The 22th International Conference on Organometallic Chemistry, Jul. 23-28, 2006, Zaragoza
年度 计画名称 职称/担任之工作 计画期间 补助/委讬或合作机构
2025 含锰、铁或钴氧合酶之仿生催化剂的反应性研究(3/3) 主持人 2024.08 ~ 2025.07 国科会
2025 含锰、铁或钴氧合酶之仿生催化剂的反应性研究(2/3) 主持人 2023.08 ~ 2025.07 国科会
2024 以奈米孔洞金属有机骨架为载体建构仿生催化剂－以金属有机骨架为载体建构可氧合碳氢化合物之仿生催化剂(3/3) 主持人 2023.08 ~ 2024.07 国科会
2025 含锰、铁或钴氧合酶之仿生催化剂的反应性研究(1/3) 主持人 2022.08 ~ 2025.07 国科会
2024 以奈米孔洞金属有机骨架为载体建构仿生催化剂－以金属有机骨架为载体建构可氧合碳氢化合物之仿生催化剂(2/3) 主持人 2022.08 ~ 2024.07 国科会
2022 中华民国参加2022年第54届国际化学奥林匹亚竞赛参赛计画 主持人 2021.10 ~ 2022.09 教育部
2024 以奈米孔洞金属有机骨架为载体建构仿生催化剂－以金属有机骨架为载体建构可氧合碳氢化合物之仿生催化剂(1/3) 主持人 2021.08 ~ 2024.07 国科会
2022 含锰或含钴氧合酶之活性中心拟态化合物之反应性研究(3/3) 主持人 2021.08 ~ 2022.07 国科会
2021 中华民国参加2021年第53届国际化学奥林匹亚竞赛参赛计画 主持人 2020.10 ~ 2021.09 教育部
2022 含锰或含钴氧合酶之活性中心拟态化合物之反应性研究(2/3) 主持人 2020.08 ~ 2022.07 国科会
2021 109-110年度化学奥林匹亚竞赛推广计画 主持人 2020.05 ~ 2021.12 教育部
2022 含锰或含钴氧合酶之活性中心拟态化合物之反应性研究(1/3) 主持人 2019.08 ~ 2022.07 国科会
2019 含铁或钴氧合酶之活性中心拟态化合物合成与反应性之研究(3/3) 主持人 2018.08 ~ 2019.07 国科会
2018 氧气活化之催化循环中具活性中间体之合成 (2/2) 主持人 2018.01 ~ 2018.12 国科会
2019 含铁或钴氧合酶之活性中心拟态化合物合成与反应性之研究 主持人 2017.08 ~ 2019.07 科技部(原国科会)
2017 氧气活化之催化循环中具活性中间体之合成 (1/2) 主持人 2017.01 ~ 2017.12 科技部(原国科会)
2017 含铁或钴氧合酶之活性中心拟态化合物合成与反应性之研究 主持人 2016.08 ~ 2017.07 科技部(原国科会)
2019 含铁或钴氧合酶之活性中心拟态化合物合成与反应性之研究 主持人 2016.08 ~ 2019.07 科技部(原国科会)
2016 含镍、锰或铁超氧化物岐化酶之活性中心拟态化合物合成与反应性之研究 主持人 2015.08 ~ 2016.07 科技部(原国科会)
2016 含镍、锰或铁超氧化物岐化酶之活性中心拟态化合物合成与反应性之研究 主持人 2014.08 ~ 2016.07 科技部(原国科会)
2016 含镍、锰或铁超氧化物岐化酶之活性中心拟态化合物合成与反应性之研究 主持人 2013.08 ~ 2016.07 科技部(原国科会)
2013 国立台湾师范大学贵重仪器使用中心服务计画 协同/共同主持人 2013.01 ~ 2013.12 国科会
2013 含镍或铜酵素之活性中心拟态化合物合成与反应性之研究 主持人 2012.08 ~ 2013.07 国科会
2012 国立台湾师范大学贵重仪器使用中心服务计画 协同/共同主持人 2012.01 ~ 2012.12 国科会
2013 含镍或铜酵素之活性中心拟态化合物合成与反应性之研究 主持人 2011.08 ~ 2013.07 国科会
2012 重点一子题2：含嘧啶或亚碳配子或C4对称氧钒中心四聚体之镍和铜错合物进行不 主持人 2011.08 ~ 2012.07 国科会
2011 国立台湾师范大学贵重仪器使用中心服务计画 协同/共同主持人 2011.01 ~ 2011.12 国科会
2012 重点一子题2---含嘧啶或亚碳配子或C4对称氧钒中心四聚体之镍和铜错合物进行不对称共轭加成及碳氢化合物氧合化反应之研究 主持人 2010.08 ~ 2012.07 国科会
2013 含镍或铜酵素之活性中心拟态化合物合成与反应性之研究 主持人 2010.08 ~ 2013.07 国科会
2010 含镍、锌或铜酵素之活性中心拟态化合物合成与相关催化反应之研究 主持人 2009.08 ~ 2010.07 国科会
2012 重点一子题2---含嘧啶或亚碳配子或C4对称氧钒中心四聚体之镍和铜错合物进行不对称共轭加成及碳氢化合物氧合化反应之研究 主持人 2009.08 ~ 2012.07 国科会
2010 镍催化剂之合成与鑑定并进行乙烯和烯烃類聚合反应之研究 主持人 2009.06 ~ 2010.08 国科会
2009 多铜氧模脢型错合物研究---漆脢及抗坏血病氧化脢 主持人 2008.08 ~ 2009.07 国科会
2010 含镍、锌或铜酵素之活性中心拟态化合物合成与相关催化反应之研究 主持人 2008.08 ~ 2010.07 国科会
2009 多铜氧模脢型错合物研究---漆脢及抗坏血病氧化脢 主持人 2007.08 ~ 2009.07 国科会
2008 含镍及含锌酵素之活性中心拟态化合物合成与相关催化反应之研究 主持人 2007.08 ~ 2008.07 国科会
2009 多铜氧模脢型错合物研究---漆脢及抗坏血病氧化脢 主持人 2006.08 ~ 2009.07 国科会
2007 含镍酵素之脲酶及甲烷辅酶M还原酶的活性中心之拟态研究(2/2) 主持人 2006.08 ~ 2007.07 国科会
2006 含镍酵素之脲酶及甲烷辅酶M还原酶的活性中心之拟态研究(1/2) 主持人 2005.08 ~ 2006.07 国科会
2005 脲酶之双镍活性中心之结构与反应性的模拟(2/2) 主持人 2004.08 ~ 2005.07 国科会
2004 脲酶之双镍活性中心之结构与反应性的模拟(1/2) 主持人 2003.11 ~ 2004.07 国科会
国家 学校名称 系所 学位 期间
美国 德州农工大学 化学系 博士 1997.01 ~ 2001.06
台湾 国立彰化师范大学 化学系 理学士 1988.09 ~ 1992.06
服务机关名称 单位 职务 期间
国立台湾师范大学 化学系 教授 2015.02 ~ 迄今
国立台湾师范大学 研发处贵仪中心 主任 2012.02 ~ 2013.07
国立台湾师范大学 研发处企画组 组长 2009.08 ~ 2011.07
国立台湾师范大学 化学系 副教授 2009.02 ~ 2015.01
国立台湾师范大学 化学系 助理教授 2003.08 ~ 2009.01
美国明尼苏达大学 化学系 博士后研究 2001.08 ~ 2003.07
类别 年度 奖项名称 颁奖单位
校内荣誉 2013 教学优良奖 国立台湾师范大学