李位仁
姓名 李位仁
電子郵件
聯絡電話 (02)77496133
網站 http://140.122.142.231/~wzlee/
實驗室電話 (02)77496186
職稱 研究講座教授
研究領域 生物無機、仿生催化、有機金屬
學術專長 研究興趣 (1)含金屬酵素之活性中心的小分子模型之合成與特性研究及光譜探討和模型與酵素間之比較,以期更了酵素催化反應之反應機制。 (2)合成仿生催化劑之金屬錯合物,以進行碳氫化合物之氧合催化反應。
指導學生 柯名時 / 張智凱 / 楊人翰 / 楊詠剴 / 蔡杰紘 / 陳志銘 / 朱允立 / 林宗翰 / 王維鈴 / 陳許志勇
實驗室 生物無機研究室
  1. T. Chatterjee, B. Molnar, W.-Z. Lee,* K. V. Lakshmi,* and M. Ravikanth* “Calixsmaragdyrin: A Versatile Ligand for Coordination Complexes” Inorg. Chem201756, 3763-3772.
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  2. J.-H. Fang, J.-H. Jian, H.-C. Chang, T.-S. Kuo, W.-Z. Lee, P.-Y. Wu, and H.-Liang Wu* "Synthesis of Quaternary-Carbon-Containing β2,2-Amino Acids by the RhI-Catalyzed Enantioselective Arylation of α-Substituted β-NitroacrylatesChem. Eur. J. 201723, 1830-1838.
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  3. C.-C. Wang, H.-C. Chang, Y.-C. Lai, H. Fang, C.-C. Li, H.-K. Hsu, Z.-Y. Li, T.-S. Lin, T.-S. Kuo, F. Neese, S. Ye,* Y.-W. Chiang,* M.-L. Tsai,* W.-F. Liaw,* and W.-Z. Lee* “A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from its Superoxo Intermediate via Hydrogen Atom Abstraction” J. Am. Chem. Soc. 2016138, 14186-14189.
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  4. T. Kaur, W.-Z. Lee and M. Ravikanth* “Rhenium(I) Tricarbonyl Complexes of meso-Tetraaryl-21,23-diheteroporphyrins” Inorg. Chem. 201655, 5305-5311.
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  5. H. D. Stout, S. T. Kleespies, C.-W. Chiang, W.-Z. Lee, L. Que, Jr., E. Münck,* and E. L. Bominaar* “Spectroscopic and Theoretical Study of Spin-Dependent Electron Transfer in an Iron(III) Superoxo Complex” Inorg. Chem. 201655, 5215-5226.
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  6. T. Kaur, W.-Z. Lee and M. Ravikanth* “N-Methylated 25-Oxasmaragdyrins: Synthesis, Structure and Properties” J. Porphyr. Phthalocyanines 201620, 582-589.
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  7. T. Chatterjee, W.-Z. Lee and M. Ravikanth* “Stabilization of Hexa-Coordinated P(V) Corroles by Axial Silyloxy Groups” Dalton. Trans201645, 7815-7822.
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  8. C.-C. Chou,* C.-C. Yang, H.-C. Chang, W.-Z. Lee* and T.-S. Kuo “Weaving an infinite 3-D supramolecular network via AuI⋯AuIII aurophilicity and C-H⋯Cl hydrogen bonding” New J. Chem201640, 1944-1947.
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  9. H.-C. Chang, Y.-C. Hsu, C.-H. Chen, T.-S. Kuo and W.-Z. Lee* “Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)–(2-mercaptophenyl)phosphine complexations” Dalton Trans201544, 20808-20811.
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  10. R. Sharma, W.-Z. Lee, and M. Ravikanth* “Formation of Unusual Dithiaphlorins from Condensation of 2,5-bis(Arylhydroxymethyl)thiophene and Pyrrole” RSC Adv. 20155, 102765-102771.
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  11. H. Kalita, W.-Z. Lee, G.-G. Theophall, K.-V. Lakshmi, and M. Ravikanth* “A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle” Chem. Eur. J. 2015, 21, 11315-11319.
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  12. E. Ganapathi, T Chatterjee, W.-Z. Lee and M. Ravikanth* “Synthesis, Structure, and Properties of Core-modified Pentaphyrins Containing Six mesoCarbons” Asian J. Org. Chem. 20154, 638-645.
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  13. H.-C. Chang, F.-C. Lo, W.-C. Liu, T.-H. Lin, W.-F. Liaw, T.-S. Kuo, and W.-Z. Lee* “Ambient Stable Trigonal Bipyramidal Copper(III) Complexes Equipped with an Exchangeable Axial Ligand” Inorg. Chem201554, 5527-5533.
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  14. Y. Meesala, V. Kavala, H.-C. Chang, T.-S. Kuo, C.-F. Yao,* and W.-Z. Lee* “Anilido-Benzoxazole Boron Difluoride (ABB) Complexes: Novel bright fluorescent dyes in solution and in the solid state” Dalton Trans201544, 1120-1129.
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  15. V. Lakshmi, W.-Z. Lee, and M. Ravikanth* "Synthesis, structure and spectral and electrochemical properties of 3-pyrrolyl BODIPY-metal dipyrrin complexesDalton Trans201443, 16006-16014.
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  16. E. Ganapathi, W.-Z. Lee,* and M. Ravikanth* "Stable Nonaromatic [20]Dithiaporphyrin (2.1.1.1) Macrocycles: Synthesis, Structure, Spectral, Electrochemical and Metal Ion Sensing Studies” J. Org. Chem. 201479, 9603-9612.
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  17. Y. Meesala, H.-L. Wu, B. Koteswararao, T.-S. Kuo, and W.-Z. Lee* “Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Hexanuclear Bis(μ-hydroxo)Copper(II) Catalyst” Organometallics 201433, 4385-4393.
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  18. H. Kalita, W.-Z. Lee, and M. Ravikanth* "Phosphorus Complexes of meso-Triaryl-25-oxasmaragdyrinsInorg. Chem. 201453, 9431-9438.
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  19. H. Kalita, D. Kalita, W.-Z. Lee, J. Bellare, and M. Ravikanth* “Synthesis of meso-Pyrrole-Substituted 22-Oxacorroles by a "3+2" Approach” Chem. Eur. J. 2014, 20, 10404-10413.
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  20. C.-W. Chiang, S. Kleespies, H. Stout, K. Meier, P.-Y. Li, E. Bominaar,* L. Que, Jr.,* E. Münck,* and W.-Z. Lee* “Characterization of a Paramagnetic Mononuclear Nonheme Iron-Superoxo Complex” J. Am. Chem. Soc. 2014136, 10846-10849.
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  21. T. Kaur, W.-Z. Lee, and M. Ravikanth* "N-Methyl-21-thiaprophyrinsEur. J. Org. Chem. 2014, 2261-2267.
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  22. C.-W. Chiang, Y.-L. Chu, H.-L. Chen, T.-S. Kuo, and W.-Z. Lee* “Synthesis and Characterization of NiIIIN3S2 Complexes as Active Site Models for the Oxidized Form of Nickel Superoxide Dismutase” Chem. Eur. J. 2014, 20, 6283-6286.
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  23. E. Ganapathi, W.-Z. Lee* and M. Ravikanth* “Synthesis, Structure, Spectral and Electrochemical Properties of Meso-Tetraaryl 27-Thiasapphyrins” Asian J. Org. Chem. 20143, 290-296.
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  24. B. Gopula, C.-W. Chiang, W.-Z. Lee, T.-S. Kuo, P.-Y. Wu, J. P. Henschke, and H.-Liang Wu* "Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to N-Tosyl IminesOrg. Lett. 201416, 632-635.
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  25. H. Kalita, W.-Z. Lee, and M. Ravikanth,* “Synthesis, structure, spectral and electrochemical properties of B(OR)2-smaragdyrin complexes” Dalton Trans. 201342, 14537-14544.
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  26. A. Ghosh, W.-Z. Lee, and M. Ravikanth* "Unusual formation of thiaisoporphyrins from 21-thiaporphyrinsChem. Commun. 201349, 8677-8679.
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  27. H. Kalita, W.-Z. Lee, and M. Ravikanth* "Synthesis and Functionalization of BF2-complexes of meso-free 25-oxasmaragdyrin” J. Org. Chem. 201378, 6285-6290.
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  28. A. Ghosh, T. Chatterjee, W.-Z. Lee, and M. Ravikanth* "Unusual Formation of 21-Oxacorrole from 21-Oxaporphyrin Induced by Phosphoryl ChlorideOrg. Lett. 201315, 1040-1043.
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  29. W.-Z. Lee,* C.-W. Chiang, G. M. Kulkarni, and T.-S. Kuo “Highly Efficient Proline Ester-Based Catalysts for Michael Addition of Thiophenols to α,β-Enones” J. Chin. Chem. Soc. 201360, 245-250.
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  30. B. Gopula, W.-Z. Lee, H.-L. Wu* “Preparation of Chiral α-Substituted Alaninates through an Efficient Diastereoselective Synthesis of Trisubstituted Allylic Alcohols” Chem. Asian J. 20138, 80-83.
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  31. A. Ghosh, W.-Z. Lee, and M. Ravikanth* "Synthesis, Structure and Properties of a Five-Coordinate Oxophosphorus(V) meso-TriphenylcorroleEur. J. Inorg. Chem. 2012, 4231-4239.
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  32. W.-Z. Lee,* T.-L. Wang, H.-C. Chang, Y.-T. Chen, and T.-S. Kuo “A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition” Organometallics 201231, 4106-4109.
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  33. W.-Z. Lee,* C.-W. Chiang, T.-H. Lin, and T.-S. Kuo “A Discrete Five-Coordinate NiIII Complex Resembling the Active Site of the Oxidized Form of Nickel Superoxide Dismutase” Chem. Eur. J. 201218, 50-53.
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  34. W.-Z. Lee,* H.-S. Tsang, T.-L. Wang, H.-L. Tsai,* and T.-S. Kuo “Bio-inspired Catalytic Conjugate Additions of Thiophenols to α,β-Enones by a Disubstituted Benzoate-Bridged Nickel Mimic for the Active Site of Urease” Organometallics 201029, 2874-2881.
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  35. W.-Z. Lee,* T.-L. Wang, H.-S. Tsang, C.-Y. Liu, and C.-T. Chen,* T.-S. Kuo “Temperature Dependant Nuclearity in bis(Benzimidazoyl) Nickel Complexes and Their Catalysis Towards Conjugate Addition of Thiophenols to α,β-Enones” Organometallics 200928, 652-655.
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  36. W.-Z. Lee,* Y.-L. Kang, T.-L. Wang, C.-C. Su,* and T.-S. Kuo “Structural Interconversion Controlled by Hydrogen-bond Interactions: A Mononuclear Copper Triamine Complex and A polynuclear Copper Triamine Sheet” Cryst. Growth Des. 20088, 2614-2616.
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  37. W.-Z. Lee,* H.-S. Tseng, M.-Y. Ku, and T.-S. Kuo, “Dinickel Complexes of Disubstituted Benzoate Polydentate Ligands: Mimics for the Active Site of Urease” Dalton Trans. 2008, 2538-2541.
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  38. C.-T. Chen,* S. Bettigeri, S.-S. Weng, V. Pawar, Y.-H. Lin, C.-Y. Liu, W.-Z. Lee,* “Asymmetric Aerobic Oxidation of alpha-Hydroxy Acid Derivatives by C4-Symmetric, Vanadate-centered, Tetrakisvanadyl(V) Clusters Derived from N-Salicylidene-alpha-aminocarboxylates” J. Org. Chem. 200772, 8175-8185.
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  39. W.-Z. Lee,* H.-S. Tseng, and T.-S. Kuo, “Ligand-Controlled Nuclearity in Nickel bis(Benzimidazolyl) Complexes” Dalton Trans. 2007, 2563-2570.
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  40. C.-H. Hung,* W.-M. Ching, G.-F. Chang, C.-H. Chuang, H.-W. Chu, and W.-Z. Lee, “Formation of a Sulfur-Atom-Inserted N-Confused Porphyrin Iron Nitrosyl Complex by Denitrosation and C-S Bond Cleavage of an S-Nitrosothiol” Inorg. Chem. 200746, 10941-10943.
     
  41. D. J. Darensbourg, W.-Z. Lee, and L. P. Andrea, “The Synthesis and Characterization of iron cyanide building blocks: [K]2[CpFe(CN)3] and its pentamethylcyclopentadienyl (Cp*) analog” Inorg. Chim. Acta 2005, 358, 4095-4098.
     
  42. D. J. Darensbourg, W.-Z. Lee, and M. J. Adams, “Phosphine Derivatives of Diamond-Shaped Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups” Inorganic Syntheses 2004, 34, 172-177.
     
  43. D. J. Darensbourg,; W.-Z. Lee, A. L. Phelps, and E. Guidry, “Kinetic Study of the Insertion and Deinsertion of Carbon Dioxide into fac-(CO)3(dppe)MnOR Derivatives” Organometallics 2003, 22, 5585-5588.
     
  44. W.-Z. Lee and W. B. Tolman, “Toward Synthetic Analogs of Linked Redox and Catalytic Multimetal Site in Proteins: A Model of the Histidine-Cysteine Bridged Dicopper Array” Inorg. Chem. 2002, 41, 5656-5658.
     
  45. D. J. Darensbourg, W.-Z. Lee, and J. C. Yarbrough, “Synthesis and Characterization of a Monocyanide-Bridged Bimetallic Iron(II) and Copper(I) Complex” Inorg. Chem. 2001, 40, 6533-6536.
     
  46. D. J. Darensbourg, W.-Z. Lee, M. J. Adams, and J. C. Yarbrough, “Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups Containing Monodentate or Bidentate Phosphanes Bound to Copper(I), Including an Alternative Structure Based on the Nature of the Bidentate Phosphane Ligand” Euro. J. Inorg. Chem. 2001, 2001, 2811-2822.
     
  47. D. J. Darensbourg, W.-Z. Lee, M. J. Adams, D. L. Larkins, and J. H. Reibenspies, “Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups” Inorg. Chem. 1999, 38, 1378-1379.
     
  48. C.-H. Lai, W.-Z. Lee, M. L. Miller, D. J. Darensbourg, and M. Y. Darensbourg, “Responses of the Fe(CN)2(CO) Unit to Electronic Changes as Related to Its Role in [NiFe]Hydrogenase” J. Am. Chem. Soc. 1998, 120, 10103-10114.
     
  49. D. J. Darensbourg, J. H. Reibenspies, C.-H. Lai, W.-Z. Lee, and M. Y. Darensbourg, “Analysis of an Organometallic Iron Site model for the Heterodimetallic Unit of [NiFe]Hydrogenase” J. Am. Chem. Soc. 1997, 119, 7903-7904.
年度 論文名稱
2022 Hydrogen Atom Transfer Thermodynamics of Homologous Co(III)- and Mn(III)-Superoxo Complexes: The Effect of the Metal Spin State, JACS Au, vol. 2, Aug. 2022
2022 Investigation of optimal conditions needed for the production of indigo and subsequent dyeing using CO2/O2 sensors and a cellphone camera, Analytical Sciences, vol. 38, May. 2022
2020 Ambiphilicity of a Mononuclear Cobalt(III) Superoxo Complex, Chem. Commun., vol. 56, Dec. 2020
2020 Redox reactions between chromium(VI) and hydroquinone: Alternative pathways for polymerization of organic molecules, Environmental Pollution, vol. 261, Jun. 2020
2020 A Manganese(IV)-Hydroperoxo Intermediate Generated by Protonation of the Corresponding Manganese(III)-Superoxo Complex, J. Am. Chem. Soc., vol. 142, Jun. 2020
2020 Insights into the chemistry and structure of iron gall ink based on “two-step” bamboo nib-spray/mass spectrometry, International Journal of Mass Spectrometry, vol. 451, May. 2020
2020 Dinitrosyliron Complex [(PMDTA)Fe(NO)2]: Intermediate for Nitric Oxide Monooxygenation Activity in Nonheme Iron Complex, Inorganic Chemistry, vol. 59, May. 2020
2019 Hydrogen Bond-Enabled Heterolytic and Homolytic Peroxide Activation within Nonheme Copper(II)-Alkylperoxo Complexes, Inorg. Chem., vol. 58, Sep. 2019
2019 Conversion of a Fleeting Open-Shell Iron Nitride into an Iron Nitrosyl, Angew. Chem. Int. Ed., vol. 58, Sep. 2019
2019 Mononuclear Manganese(III) Superoxo Complexes: Synthesis, Characterization, and Reactivity, Inorg. Chem., vol. 58, Aug. 2019
2019 Ambient Stable Cyanomethylcopper(III) Complex: A Strong Cu-Csp 3 Bond Supported by a PS3-Tripodal Chelator, Inorg. Chem., vol. 58, Jan. 2019
2018 Synthesis, Structural, Spectral, and Electrochemical Studies of Selenabenziporphyrin and Its Pd(II) Complex, Inorg. Chem., vol. 57, Aug. 2018
2018 Synthesis of Tellurabenziporphyrin and Its Pd(II) Complex, Org. Lett., vol. 30, Mar. 2018
2018 Nickel(III)-mediated oxidative cascades from a thiol-bearing nickel(II) precursor to the nickel(IV) product, Dalton Transactions, vol. 47, Jan. 2018
2017 Construction of Novel Cyclic Tetrads by Axial Coordination of Thiaporphyrins to Tin(IV) Porphyrin, Inorg. Chem., vol. 56, Nov. 2017
2017 Hybrid Macrocycles of Subporphyrins and Triphyrins, Org. Lett., vol. 19, Nov. 2017
2017 Synthetic nickel-containing superoxide dismutase attenuates para-phenylenediamine-induced bladder dysfunction in rats, Oncotarget, vol. 21, Nov. 2017
2017 Synthesis of Quaternary-Carbon-Containing β2,2-Amino Acids by the RhI-Catalyzed Enantioselective Arylation of α-Substituted β-Nitroacrylates, Chem. Eur. J., vol. 23, Oct. 2017
2017 Calixsmaragdyrin: A Versatile Ligand for Coordination Complexes, Inorg. Chem., vol. 56, Apr. 2017
2016 A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from its Superoxo Intermediate via Hydro-gen Atom Abstraction, J. Am. Chem. Soc., vol. 138, Nov. 2016
2016 Rhenium(I) Tricarbonyl Complexes of meso-Tetraaryl-21,23-diheteroporphyrins, Inorg. Chem., vol. 55, Jun. 2016
2016 Spectroscopic and Theoretical Study of Spin-Dependent Electron Transfer in an Iron(III) Superoxo Complex, Inorg. Chem., vol. 55, Jun. 2016
2016 N-methylated 25-oxasmaragdyrins: Synthesis, structure and properties, J. Porphyrins Phthalocyanines, vol. 20, May. 2016
2016 Stabilization of hexa-coordinated P(V) corroles by axial silyloxy groups, Dalton Transactions, vol. 45, Mar. 2016
2016 Ring Opening of a meso-Triaryl 25-Oxasmaragdyrin Macrocycle by m-Chloroperoxybenzoic Acid, Chem. Eur. J., vol. 22, Feb. 2016
2016 Weaving an infinite 3-D supramolecular network via AuI⋅⋅⋅AuIII aurophilicity and C-H⋅⋅⋅Cl hydrogen bonding, New. J. Chem., vol. 40, Jan. 2016
2015 Formation of unusual dithiaphlorins from condensation of 2,5-bis(arylhydroxymethyl)thiophene and pyrrole, RSC Advances, vol. 5, Dec. 2015
2015 Thioiminium and thiaphospholanium derived from acetonitrile via nickel(II)–(2-mercaptophenyl)phosphine complexation, Dalton Trans., vol. 44, Dec. 2015
2015 A Stable Seven-Membered Heterocycle, Containing B, C, N, O, and P Atoms, inside a Smaragdyrin Macrocycle, Chem. Eur. J., vol. 21, Aug. 2015
2015 Synthesis, Structure, and Properties of Core-modified Pentaphyrins Containing Six mesoCarbons, Asian. J. Org. Chem., vol. 2015, Jul. 2015
2015 Ambient Stable Trigonal Bipyramidal Copper(III) Complexes Equipped with an Exchangeable Axial Ligand, Inorg. Chem., vol. 54, May. 2015
2014 Synthesis, structures and electrochemical and photophysical properties of anilido-benzoxazole boron difluoride (ABB) complexes, Dalton Trans., vol. 44, Nov. 2014
2014 Synthesis, structure and spectral and electrochemical properties of 3-pyrrolyl BODIPY-metal dipyrrin complexes, Dalton Trans., vol. 43, Nov. 2014
2014 Stable Nonaromatic [20]Dithiaporphyrin (2.1.1.1) Macrocycles: Synthesis, Structure, Spectral, Electrochemical and Metal Ion Sensing Studies, J. Org. Chem., vol. 79, Oct. 2014
2014 Aerobic Oxidative Coupling of 2-Naphthol Derivatives Catalyzed by a Hexanuclear Bis(μ-hydroxo)Copper(II) Catalyst, Organometallics, vol. 33, Sep. 2014
2014 Phosphorus Complexes of meso-Triaryl-25-oxasmaragdyrins, Inorg. Chem., vol. 53, Sep. 2014
2014 Synthesis of meso-Pyrrole-Substituted 22-Oxacorroles by a "3+2" Approach, Chem. Eur. J., vol. 20, Aug. 2014
2014 Characterization of a Paramagnetic Mononuclear Nonheme Iron-Superoxo Complex, J. Am. Chem. Soc., vol. 136, Jul. 2014
2014 N-Methyl-21-thiaprophyrins, Eur. J. Org. Chem., vol. 2014, Jun. 2014
2014 Synthesis and Characterization of NiIIIN3S2 Complexes as Active Site Models for the Oxidized Form of Nickel Superoxide Dismutase, Chem. Eur. J., vol. 20, May. 2014
2014 Synthesis, Structure, Spectral and Electrochemical Properties of Meso-Tetraaryl 27-Thiasapphyrins, Asian. J. Org. Chem., vol. 3, Mar. 2014
2014 Highly Enantioselective Rh-Catalyzed Alkenylation of Imines: Synthesis of Chiral Allylic Amines via Asymmetric Addition of Potassium Alkenyltrifluoroborates to N-Tosyl Imines, Org. Lett., vol. 16, Jan. 2014
2013 Synthesis, structure, spectral and electrochemical properties of B(OR)2-smaragdyrin complexes, Dalton Trans., vol. 42, Oct. 2013
2013 Unusual formation of thiaisoporphyrins from 21-thiaporphyrins, Chem. Commun., vol. 49, Oct. 2013
2013 Synthesis and Functionalization of BF2-complexes of meso-free 25-oxasmaragdyrin, J. Org. Chem., vol. 78, Jun. 2013
2013 Unusual Formation of 21-Oxacorrole from 21-Oxaporphyrin Induced by Phosphoryl Chloride, Org. Lett., vol. 15, Mar. 2013
2013 Highly Efficient Proline Ester-Based Catalysts for Michael Addition of Thiophenols to α,β-Enones, J. Chin. Chem. Soc., vol. 60, Mar. 2013
2013 Preparation of Chiral α-Substituted Alaninates through an Efficient Diastereoselective Synthesis of Trisubstituted Allylic Alcohols, Chem. Asian J., vol. 8, Jan. 2013
2012 Synthesis, Structure and Properties of a Five-Coordinate Oxophosphorus(V) meso-Triphenylcorrole, Eur. J. Inorg. Chem., vol. 2012, Sep. 2012
2012 A Bioinspired ZnII/FeIII Heterobimetallic Catalyst for Thia-Michael Addition, Organometallics, vol. 31, May. 2012
2012 A Discrete Five-Coordinate NiIII Complex Resembling the Active Site of the Oxidized Form of Nickel Superoxide Dismutase, Chem. Eur. J., vol. 18, Jan. 2012
2010 Bio-inspired Catalytic Conjugate Additions of Thiophenols to ,-Enones by a Disubstituted Benzoate-Bridged Nickel Mimic for the Active Site of Urease, Organometallics, vol. 29, Jun. 2010
2009 Urease and Its Synthetic Mimics, Chemistry, vol. 67, Jun. 2009
2009 Temperature Dependant Nuclearity in bis(Benzimidazoyl) Nickel Complexes and Their Catalysis Towards Conjugate Addition of Thiophenols to α,β-Enones, Organometallics, vol. 28, Jan. 2009
2008 Dinickel Complexes of Disubstituted Benzoate Polydentate Ligands: Mimics for the Active Site of Urease, Dalton Trans., Mar. 2008
2008 Structural Interconversion Controlled by Hydrogen-bond Interactions: A Mononuclear Copper Triamine Complex and A polynuclear Copper Triamine Sheet, Cryst. Growth Des., vol. 8, Jan. 2008
2007 Formation of a Sulfur-Atom-Inserted N-Confused Porphyrin Iron Nitrosyl Complex by Denitrosation and C-S Bond Cleavage of an S-Nitrosothiol, Inorg. Chem., vol. 46, Nov. 2007
2007 Asymmetric Aerobic Oxidation of alpha-Hydroxy Acid Derivatives by C4-Symmetric, Vanadate-centered, Tetrakisvanadyl(V) Clusters Derived from N-Salicylidene-alpha-aminocarboxylates, J. Org. Chem., vol. 72, Apr. 2007
2007 Ligand-Controlled Nuclearity in Nickel Bis(benzimidazolyl)Complexes, Dalton Trans., Apr. 2007
年度 計畫名稱 職稱/擔任之工作 計畫期間 補助/委託或合作機構
2025 含錳、鐵或鈷氧合酶之仿生催化劑的反應性研究(3/3) 主持人 2024.08 ~ 2025.07 國科會
2025 含錳、鐵或鈷氧合酶之仿生催化劑的反應性研究(2/3) 主持人 2023.08 ~ 2025.07 國科會
2024 以奈米孔洞金屬有機骨架為載體建構仿生催化劑-以金屬有機骨架為載體建構可氧合碳氫化合物之仿生催化劑(3/3) 主持人 2023.08 ~ 2024.07 國科會
2025 含錳、鐵或鈷氧合酶之仿生催化劑的反應性研究(1/3) 主持人 2022.08 ~ 2025.07 國科會
2024 以奈米孔洞金屬有機骨架為載體建構仿生催化劑-以金屬有機骨架為載體建構可氧合碳氫化合物之仿生催化劑(2/3) 主持人 2022.08 ~ 2024.07 國科會
2022 中華民國參加2022年第54屆國際化學奧林匹亞競賽參賽計畫 主持人 2021.10 ~ 2022.09 教育部
2024 以奈米孔洞金屬有機骨架為載體建構仿生催化劑-以金屬有機骨架為載體建構可氧合碳氫化合物之仿生催化劑(1/3) 主持人 2021.08 ~ 2024.07 國科會
2022 含錳或含鈷氧合酶之活性中心擬態化合物之反應性研究(3/3) 主持人 2021.08 ~ 2022.07 國科會
2021 中華民國參加2021年第53屆國際化學奧林匹亞競賽參賽計畫 主持人 2020.10 ~ 2021.09 教育部
2022 含錳或含鈷氧合酶之活性中心擬態化合物之反應性研究(2/3) 主持人 2020.08 ~ 2022.07 國科會
2021 109-110年度化學奧林匹亞競賽推廣計畫 主持人 2020.05 ~ 2021.12 教育部
2022 含錳或含鈷氧合酶之活性中心擬態化合物之反應性研究(1/3) 主持人 2019.08 ~ 2022.07 國科會
2019 含鐵或鈷氧合酶之活性中心擬態化合物合成與反應性之研究(3/3) 主持人 2018.08 ~ 2019.07 國科會
2018 氧氣活化之催化循環中具活性中間體之合成 (2/2) 主持人 2018.01 ~ 2018.12 國科會
2019 含鐵或鈷氧合酶之活性中心擬態化合物合成與反應性之研究 主持人 2017.08 ~ 2019.07 科技部(原國科會)
2017 氧氣活化之催化循環中具活性中間體之合成 (1/2) 主持人 2017.01 ~ 2017.12 科技部(原國科會)
2017 含鐵或鈷氧合酶之活性中心擬態化合物合成與反應性之研究 主持人 2016.08 ~ 2017.07 科技部(原國科會)
2019 含鐵或鈷氧合酶之活性中心擬態化合物合成與反應性之研究 主持人 2016.08 ~ 2019.07 科技部(原國科會)
2016 含鎳、錳或鐵超氧化物岐化酶之活性中心擬態化合物合成與反應性之研究 主持人 2015.08 ~ 2016.07 科技部(原國科會)
2016 含鎳、錳或鐵超氧化物岐化酶之活性中心擬態化合物合成與反應性之研究 主持人 2014.08 ~ 2016.07 科技部(原國科會)
2016 含鎳、錳或鐵超氧化物岐化酶之活性中心擬態化合物合成與反應性之研究 主持人 2013.08 ~ 2016.07 科技部(原國科會)
2013 國立台灣師範大學貴重儀器使用中心服務計畫 協同/共同主持人 2013.01 ~ 2013.12 國科會
2013 含鎳或銅酵素之活性中心擬態化合物合成與反應性之研究 主持人 2012.08 ~ 2013.07 國科會
2012 國立台灣師範大學貴重儀器使用中心服務計畫 協同/共同主持人 2012.01 ~ 2012.12 國科會
2013 含鎳或銅酵素之活性中心擬態化合物合成與反應性之研究 主持人 2011.08 ~ 2013.07 國科會
2012 重點一子題2:含嘧啶或亞碳配子或C4對稱氧釩中心四聚體之鎳和銅錯合物進行不 主持人 2011.08 ~ 2012.07 國科會
2011 國立台灣師範大學貴重儀器使用中心服務計畫 協同/共同主持人 2011.01 ~ 2011.12 國科會
2012 重點一子題2---含嘧啶或亞碳配子或C4對稱氧釩中心四聚體之鎳和銅錯合物進行不對稱共軛加成及碳氫化合物氧合化反應之研究 主持人 2010.08 ~ 2012.07 國科會
2013 含鎳或銅酵素之活性中心擬態化合物合成與反應性之研究 主持人 2010.08 ~ 2013.07 國科會
2010 含鎳、鋅或銅酵素之活性中心擬態化合物合成與相關催化反應之研究 主持人 2009.08 ~ 2010.07 國科會
2012 重點一子題2---含嘧啶或亞碳配子或C4對稱氧釩中心四聚體之鎳和銅錯合物進行不對稱共軛加成及碳氫化合物氧合化反應之研究 主持人 2009.08 ~ 2012.07 國科會
2010 鎳催化劑之合成與鑑定並進行乙烯和烯烴類聚合反應之研究 主持人 2009.06 ~ 2010.08 國科會
2009 多銅氧模脢型錯合物研究---漆脢及抗壞血病氧化脢 主持人 2008.08 ~ 2009.07 國科會
2010 含鎳、鋅或銅酵素之活性中心擬態化合物合成與相關催化反應之研究 主持人 2008.08 ~ 2010.07 國科會
2009 多銅氧模脢型錯合物研究---漆脢及抗壞血病氧化脢 主持人 2007.08 ~ 2009.07 國科會
2008 含鎳及含鋅酵素之活性中心擬態化合物合成與相關催化反應之研究 主持人 2007.08 ~ 2008.07 國科會
2009 多銅氧模脢型錯合物研究---漆脢及抗壞血病氧化脢 主持人 2006.08 ~ 2009.07 國科會
2007 含鎳酵素之脲酶及甲烷輔酶M還原酶的活性中心之擬態研究(2/2) 主持人 2006.08 ~ 2007.07 國科會
2006 含鎳酵素之脲酶及甲烷輔酶M還原酶的活性中心之擬態研究(1/2) 主持人 2005.08 ~ 2006.07 國科會
2005 脲酶之雙鎳活性中心之結構與反應性的模擬(2/2) 主持人 2004.08 ~ 2005.07 國科會
2004 脲酶之雙鎳活性中心之結構與反應性的模擬(1/2) 主持人 2003.11 ~ 2004.07 國科會
國家 學校名稱 系所 學位 期間
美國 德州農工大學 化學系 博士 1997.01 ~ 2001.06
臺灣 國立彰化師範大學 化學系 理學士 1988.09 ~ 1992.06
服務機關名稱 單位 職務 期間
國立臺灣師範大學 化學系 教授 2015.02 ~ 迄今
國立臺灣師範大學 研發處貴儀中心 主任 2012.02 ~ 2013.07
國立臺灣師範大學 研發處企畫組 組長 2009.08 ~ 2011.07
國立臺灣師範大學 化學系 副教授 2009.02 ~ 2015.01
國立臺灣師範大學 化學系 助理教授 2003.08 ~ 2009.01
美國明尼蘇達大學 化學系 博士後研究 2001.08 ~ 2003.07
類別 年度 獎項名稱 頒獎單位
校內榮譽 2013 教學優良獎 國立台灣師範大學